Photolytic codeposition generation of the HgF radical in an argon matrix at 12 K: An ESR investigation
ACS Citation
Knight, L. B. Photolytic codeposition generation of the HgF radical in an argon matrix at 12 K: An ESR investigation. J. Chem. Phys. 1981, 74, 6009-6009.
Version of Record
Abstract
The HgF radical has been generated by photolysis during the codeposition reaction of Hg atoms and F2(g) in an argon matrix at 12 K. The magnetic parameters are g(∥) = 1.993(1), g ⊥ = 1.961(1); A ∥ (19F) = 1344(10) MHz, A ⊥ (19F) = 195(5), A ∥ (199Hg) = 22-‰622(10), A ⊥(199Hg) = 21-‰880(8), A ∥ (201Hg) = 8055(12), A ⊥ (201Hg) = 7760(10). Utilizing the g and Atensor data, the electronic structure of HgF is compared to the other MF radicals studied.
Source Name
Journal of Chemical Physics
Publication Date
1-1-1981
Volume
74
Issue
11
Page(s)
365-371
Document Type
Citation
Citation Type
Article
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