Title

Synthesis of a Lewis acid bearing cyclopentadienyl ligand and its tricarbonylmanganese(I) complex

ACS Citation

Watson, R. T.; Basinger, J.; Min, E. Y.; Wagenknecht, P. S. Synthesis of a Lewis acid bearing cyclopentadienyl ligand and its tricarbonylmanganese(I) complex. J. Organomet. Chem. 2005, 690, 2159-2162.

Abstract

The synthesis of a bimetallic compound comprising a Lewis acidic organochlorostannane and a transition metal carbonyl is reported. The target complex, (CO)3Mn(η5-C5H4(CH2)3SnMe2Cl)], 2, is prepared in four steps. The final step involves an exchange reaction between (CO)3Mn(η5-C5H4(CH2)3SnMe3)], 1, and SnMe2Cl2. Infrared spectroscopy demonstrates no interaction between the Lewis acid and lone pair on the carbonyl oxygen.

Source Name

Journal of Organometallic Chemistry

Publication Date

1-1-2005

Volume

690

Issue

9

Page(s)

481-485

Document Type

Citation

Citation Type

Article