Title

Competition between single and double electron transfer in collisions of doubly charged molecular pyrrole ions with neutral pyrrole molecules

ACS Citation

SedgwickK, J. B.; Paulson, B. P.; Shields, G. C.; Moran, T. F. Competition between Single and Double Electron Transfer in Collisions of Doubly Charged Molecular Pyrrole Ions with Neutral Pyrrole Molecules. Int. J. Mass Spectrom. Ion Process. 1987, 79 (1), 127-€“140.

Abstract

Cross-sections have been determined for one- and two-electron transfer channels in the collisions of keV gas-phase doubly charged pyrrole ions with pyrrole molecules. Measured single and double electron transfer total cross-sections approximate 45 {\AA}2 and 15 {\AA}2, respectively. A combination of symmetric resonance charge exchange and multistate curve-crossing models has been invoked to describe these reactions.

Source Name

International Journal of Mass Spectrometry and Ion Processes

Publication Date

1987

Volume

79

Issue

1

Page(s)

127-140

Document Type

Citation

Citation Type

Article