Title

Emissive chromium(III) complexes with substituted arylethynyl ligands

ACS Citation

Grisenti, D. L.; Thomas, W. W.; Turlington, C. R.; Newsom, M. D.; Priedemann, C. J.; VanDerveer, D. G.; Wagenknecht, P. S. Emissive chromium(III) complexes with substituted arylethynyl ligands. Inorg. Chem. 2008, 47, 11452-4.

Abstract

Arylethynylchromium(III) complexes of the form trans-Cr(cyclam)(CCC(6)H(4)R)(2)]OTf (where cyclam = 1,4,8,11-tetraazacyclotetradecane, R = H, CH(3), or CF(3) in the para position, and OTf = trifluoromethanesulfonate) have been prepared and characterized by IR spectroscopy and X-ray diffraction. The complexes are emissive with excited-state lifetimes in a deoxygenated fluid solution between 200 and 300 micros.

Source Name

Inorganic Chemistry

Publication Date

1-1-2008

Volume

47

Issue

24

Page(s)

177-180

Document Type

Citation

Citation Type

Article