Synthesis, characterization and polymerization of metal pyrrolyl complexes
ACS Citation
Hanks, T. W.; Mathis, M.; Harsha, W. Synthesis, characterization and polymerization of metal pyrrolyl complexes. Synth. Met. 1999, 102, 1792-1793.
Version of Record
Abstract
Four new pyrrolyl complexes of Ni(II) and Pd(II) have been prepared and characterized. These complexes undergo oxidative polymerization to give semiconducting materials with conductivities as high as 0.025 S/cm. When polymerized in the presence of dodecylbenzenesulfonic acid, the polymers are soluble in organic solvents and may be cast into high quality films. The polymer prepared from (6-phenyl-2,2-€²-bipyridine)pyrrolylpalladium(II) is strongly photoluminescent.
Source Name
Synthetic Metals
Publication Date
1-1-1999
Volume
102
Issue
1-3
Page(s)
1611-1613
Document Type
Citation
Citation Type
Article
COinS