Soluble Organoiron Derivatives of Polypyrrole

Authors

Kyle Martin, Furman UniversityFollow
Timothy W. Hanks, Furman UniversityFollow

ACS Citation

Martin, K.; Hanks, T. W. Soluble Organoiron Derivatives of Polypyrrole. Organometallics 1997, 16, 4857-4860.

Version of Record

10.1021/om970257e

Abstract

Treatment of Fe(?5-C5H5)(?1-NC4H4)(CO)2 (1) with N(Bu)4S208 in the presence of dodecylbenzenesulfonic acid leads to the formation of a soluble, electrically conducting polymer (2). Solutions of 2 lose CO upon heating to give a new polymer, 3, which is postulated to contain primarily azaferrocene units in the backbone. Treatment of Fe(?5-C5H5)(?1-NC4H4)(CO)2 (1) with N(Bu)4S208 in the presence of dodecylbenzenesulfonic acid leads to the formation of a soluble, electrically conducting polymer (2). Solutions of 2 lose CO upon heating to give a new polymer, 3, which is postulated to contain primarily azaferrocene units in the backbone.

Source Name

Organometallics

Publication Date

1-1-1997

Volume

16

Issue

22

Page(s)

13266-75

Document Type

Citation

Citation Type

Article