Synthesis of Polydiacetylene Charge-Transfer Complexes
ACS Citation
Phelps, D.; Crihfield, A.; Hartwell, J.; Hanks, T. W.; Pennington, W. T.; Bailey, R. D. Synthesis of Polydiacetylene Charge-Transfer Complexes. Mol. Cryst. Liq. Cryst. Sci. Technol. , Sect. A 2000, 354, 523-530.
Version of Record
Abstract
Like 1,4-bis(3-quinolyl)buta-1,3-diyne, its structural isomer, 1,4-bis(4-isoquinolyl)buta-1,3-diyne, undergoes both photo- and thermal polymerization. Thermal polymerization of each material leads to more amorphous, less thermally stable polymers than are observed in the respective photopolymerization. The diacetylenes are found to react with certain organoiodines to give N-I charge-transfer complexes. Thermolysis of the complexes evolves the organoiodine species prior to polymerization of the diacetylene. The complexes fail to polymerize upon photolysis.
Source Name
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Publication Date
1-1-2000
Volume
354
Issue
1
Page(s)
117-120
Document Type
Citation
Citation Type
Article