Molecular charge-transfer cross sections and their correlation with reactant ion structures

ACS Citation

Shields, G. C.; Moran, T. F. Molecular Charge-Transfer Cross Sections and Their Correlation with Reactant Ion Structures. J. Phys. Chem. 1985, 89 (19), 4027-€“4031.

Abstract

Charge-transfer cross sections have been obtained by using time-of-flight techniques, and results correlated with reaction energetics and theoretical structures computed by self-consistent field-molecular orbital methods. Ion recombination energies, structures, heats of formation, reaction energy defects, and 3.0-keV charge-transfer cross sections are presented for reactions of molecular and fragment ions produced by electron bombardment ionization of CH30CH, and CH{\$}l molecules. Relationships between experimental cross sections and reaction energetics involving different ion structures are discussed.

Source Name

Journal of Physical Chemistry

Publication Date

1985

Volume

89

Issue

19

Page(s)

4027-4031

Document Type

Citation

Citation Type

Article

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