"Sensitivity of charge transfer reactions to hydrocarbon ion structures" by George C. Shields, L. Wennberg et al.
 

Sensitivity of charge transfer reactions to hydrocarbon ion structures

ACS Citation

Shields, G. C.; Wennberg, L.; Wilcox, J. B.; Moran, T. F. Sensitivity of Charge Transfer Reactions to Hydrocarbon Ion Structures. Org. Mass Spectrom. 1986, 21 (3), 137-€“149.

Abstract

Charge transfer reactivities of hydrocarbon ions have been measured with time-of-flight techniques, and results correlated with theoretical structures computed by self-consistent field molecular orbital methods. Recombination energies, ion structures, heats of formation, reaction energetics and relative charge transfer cross-sections are presented for molecular and fragment ions produced by electron bombardment ionization of CH4, C2H4, C2H6, C3H8 and C4H10 molecules. Even-electron bridged cations have low ion recombination energies and relatively low charge transfer cross-sections as compared with odd-electron hydrocarbon cations.

Source Name

Organic Mass Spectrometry

Publication Date

1986

Volume

21

Issue

3

Page(s)

137-149

Document Type

Citation

Citation Type

Article

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